Amidation of Benzyl alcohol in supercritical water without catalyst

Authors

  • Nasrin Jewena Department of Chemistry, Jahangirnagar University, Savar, Dhaka 1342, BANGLADESH.
  • Oyahida Akmam Department of Chemistry, Jahangirnagar University, Savar, Dhaka 1342, BANGLADESH.
  • Mitsuru Sasaki Institute of Pulsed Power Science, Kumamoto University, Kumamoto 860- 8555, JAPAN.

Keywords:

Supercritical water, Amination, Benzyl alcohol, Batch reactor, GCMS spectroscopy

Abstract

The amidation of benzyl alcohol was carried out in supercritical water at 400 ºC and at pressure 22 MPa for 1 hour. The replacement of the hydroxyl group with the amino group was found to proceed in benzyl alcohol using ammonium acetate in supercritical water without the addition of any catalyst. The final product N-benzalacetamide was identified by GC-MS spectroscopy.

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Published

01-06-2019

How to Cite

Nasrin Jewena, Oyahida Akmam, & Mitsuru Sasaki. (2019). Amidation of Benzyl alcohol in supercritical water without catalyst. Jahangirnagar University Journal of Science, 42(1), 75–82. Retrieved from https://jos.ju-journal.org/jujs/article/view/22

Issue

Vol. 42 No. 1: June 2019

Section

Articles

License

©2024 Jahangirnagar University Journal of Science. All rights reserved. However, permission is granted to quote from any article of the journal, to photocopy any part or full of an article for education and/or research purpose to individuals, institutions, and libraries with an appropriate citation in the reference and/or customary acknowledgement of the journal.